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Fluorine could energize fuel cells, superconductors

 

Researchers working for the Pentagon’s Threat Reduction Agency and the National Science Foundation have demonstrated that fluorine can be compressed into both a semiconductor and crystalline metal.

Applications could range from an ultra-powerful oxidizer for destroying toxic microbes to super-efficient fuel cells to room-temperature superconductors.

“We have, for the first time, metalized fluorine,” claimed researcher Choong-Shik Yoo of Washington State University. “We have proven the concept that under the right conditions, fluorine can exhibit the novel properties of both a semiconductor and a crystalline metal.”

By inserting xenon di-fluoride (XeF2, a material used to etch silicon conductors) between two diamond anvils and applying almost half-a-million atmospheres (50 GPa), the researchers produced a two-dimensional graphite-like semiconductor. The application of almost 1 million atmospheres (100 Gpa) yielded crystalline metal.

In this state, the highly concentrated fluorine could kill toxic microbes in seconds. Moreover, the energy used to compress it could be recovered as electricity from a modified fuel-cell.

“This material could be used like in a fuel-cell like device. It would not have a separate fuel and oxidizer, but its operation would be similar in that chemical energy would be stored and could be released as electricity,” said Yoo.

The researchers said their next step will be to synthesize the materials on a larger scale and find ways to stabilize them under ambient conditions. Applications also could include superconducting materials.

“There is theoretical work, which has not been published yet, that indicates that superconductivity may be achieved in these fluorine materials,” said Yoo.

July 8, 2010 - 10:52 AM No Comments

Hydrogen distribution not an option in biomass gasification

 

When using fuel cells to generate electricity from biomass, the best approach is to do so centrally, in combination with a gas turbine. The production and subsequent distribution of hydrogen is an inefficient process. This is the view of Richard Toonssen, who will defend his doctoral dissertation on this subject at TU Delft on Thursday 8 July.

Sustainable

Biomass is seen as a renewable energy source for the production of electricity and heat. The conversion of biomass for this purpose must, of course, be as efficient as possible. With this in mind, biomass gasification in combination with the use of fuel cell systems could be a very promising technology (in the future). Richard Toonssen of TU Delft compared suitable conversion chains.

Syngas

In the first conversion chain that Richard Toonssen studied, biomass is first centrally converted into syngas (a mixture of hydrogen and carbon monoxide). This gas is then used directly in fuel cells (of the SOFC type), in combination with a gas turbine, to produce electricity. The electricity generated in this way is distributed through the grid for household use. Some of this electricity is used to power household heat pumps, for heating purposes.

Gaseous

The second conversion chain that Richard Toonssen examined also starts with the centralised conversion of biomass into syngas. This is then reprocessed into a gaseous fuel (clean syngas, hydrogen, or synthetic natural gas). The fuel is then distributed to customers via a supply network. The customers in question are households that use this fuel in micro-cogeneration/coupling systems, consisting of a fuel-cell system and a heat pump.

Efficiency

The distribution of syngas is the most efficient variant of this second chain, closely followed by synthetic natural gas. According to Richard Toonssen, the variant involving the distribution of hydrogen is the least efficient of the three. The major conclusion here is that, in this case, hydrogen is an unsuitable energy carrier. Electricity is a better option.

However, none of the second conversion chain options are as promising as the first chain which, as stated above, involves the central conversion of biomass into electricity in a combined fuel-cell/gas-turbine system. 

For further information, please contact:

Richard Toonssen, Energy Technology section, Faculty of Mechanical, Maritime and Materials Engineering, TU Delft. Tel: +31-(0)15-2782153, e-mail: r.toonssen@tudelft.nl.

Ineke Boneschansker, TU Delft science information officer. Tel: +31-(0)15-2788499, e-mail: i.boneschansker@tudelft.nl.

July 8, 2010 - 10:44 AM No Comments

Buerstner and EFOY support motor home rallye Paris-Peking-Paris

 

paris_peking_paris_ii_webBrunnthal/Munich and Kehl, Germany, – Buerstner, leading international motor home and caravan manufacturer, and EFOY support the French retailer ETS Jacqueline SAS and the race team of Dominique and Anne-Marie Ribaut in the Paris-Peking-Paris rallye. In this transcontinental motor home race, 50 teams will cover around 30,000 km (approx. 18,640 miles) in their motor homes from June 1 to September 3, 2010. The rallye will start and end in Paris, crossing 13 countries – among them Germany, Poland, the Baltic States, Russia, Kazakhstan, and China. The French Federation of Camping & Caravaning (FFCC) organizes the event, following the idea of the Peking – Paris race, the world’s first and still longest transcontinental car race. The Ribaut couple competes the race with their Buerstner Solano T690-G, one of Europe’s most successful partially integrated motor home models combining dynamic driving characteristics with ultimate comfort and driving safety. An EFOY 2200 fuel cell ensures the vehicle’s off-grid power autonomy. It provides a reliable, silent, environmentally friendly power supply directly on board. During a stopover of the team on their way in early June, Buerstner and EFOY representatives welcomed Mr. and Mrs Ribaut at the Buerstner customer center in Kehl, Germany.

paris_peking_paris_i_web“We wish Dominique and Anne-Marie Ribaut much success for their trip. Our Solano proves just how comfortably and environmentally friendly this adventure can be tackled. The Solano’s dynamic driving characteristics, its on-board comfort, and its ultimate driving safety are the best prerequisites for a successful race”, says Maggie Sattler, Marketing Director France at Buerstner.

“We are proud that our EFOY 2200 is part of this race. Our fuel cell guarantees the Ribauts a reliable, silent and emission free 24/7 power supply, thus ensuring ultimate flexibility and comfort on this demanding trip. We wish the Ribauts success and luck for their exciting adventure!” says Dr. Peter Podesser, CEO of SFC Smart Fuel Cell AG. 

Additional information at efoy.com and buerstner.com

About SFC Smart Fuel Cell AG
SFC Smart Fuel Cell AG (www.sfc.com) is market leader in fuel cell technologies for mobile and off-grid power applications serving the leisure, industrial and defense markets. As one of Germany’s technology pioneers, SFC has won numerous innovation awards.  SFC has alli-ances with leading companies in a wide range of industries.  Unlike most other fuel cell manufacturers, who are in the research and development phase or run subsidized demon-stration projects, SFC has shipped more than 18,000
fully commercial products to industrial and private end users for more than five years, and has created a convenient fuel cartridge supply infrastructure. SFC is DIN ISO 9001:2000 certified. SFC is based in Brunnthal, Ger-many, and has a U.S. sales and technical service office in the U.S. SFC Smart Fuel Cell AG is listed at the Deutsche Boerse Prime Standard (WKN 756857).

About Buerstner GmbH
Buerstner GmbH (www.buerstner.com) is one of Europe’s leading caravan and motor home manufacturers with a corporate history of over fifty years. Buerstner’s roots go back to 1924 when everything started with carpentry and joinery workshops. Since then the company has dealt in woodwork and wood processing, acquiring extensive experience and competencies in this field. Today, Buerstner products are sold in more than 25 countries, mainly in Europe, by approx. 280 specialized retailers. The
Buerstner philosopy “Grenzenlos wohlfühlen – Feel great wherever you are” has long since become part of the caravaning experience of camping fans all across Europe, not least because for them tradition and innovation are combined in the Buerstner brand in a most attractive way.

July 8, 2010 - 8:00 AM No Comments

Standard on fuel cell source being drafted

 

CHINA is drafting a technical standard on fuel cell back-up power source which has advantages over conventional batteries and it is also more friendly to the environment, according to industry insiders.

The standard, with input from domestic firms, including China Mobile, China Telecom and telecom equipment producer Huawei Technologies Co, has been under scrutiny after it was submitted to the Ministry of Industry and Information Technology, a source told Shanghai Daily yesterday.

It is expected to be released as early as the end of this year, the source said.

Fuel cell back-up power source is becoming more popular as it is light, can generate more power and has better durability compared to lead-acid batteries. It is also more environmental-friendly without risks of lead pollution.

Many countries have adopted the new technology in telecom companies’ base stations in hospitals and banks.

Shanghai Peal Hydrogen Power Source Technology Co Ltd, which is involved in the draft of the standard, is testing most of its power source to ensure that it meets standards, Shi Tao, an official of the firm, said.

“A national standard is needed to direct industrial development in China and also regulate international cooperation,” said Shi.

The Shanghai-based company, which has received a US$3 million investment from venture capital firms, plans to boost the capacity to 1,000 kilowatts per year by February 2011, up from the existing 500 kilowatts.

Some analysts said despite the national standard, the green technology also faces other challenges, such as high costs, before market demand can take off. The United States government offers a subsidy of US$3,000 for each kilowatt to US producers.

July 8, 2010 - 7:51 AM No Comments

Savannah River National Laboratory’s Dr. Ragaiy Zidan Honored for Innovative Research

AIKEN, SC – - Research that is expected to accelerate the development of a whole class of hydrogen storage materials has earned the Savannah River National Laboratory’s Dr. Ragaiy Zidan a U.S. Department of Energy Hydrogen Program Team Award.

The award was presented at an audience of nearly 1,000, by the DOE Office of Energy Efficiency and Renewable Energy at its Annual Merit Review and Peer Evaluation Meeting for hydrogen, fuel cells and advanced vehicle technologies including batteries and related research. Each year, this meeting showcases projects funded by DOE. As part of the annual meeting, DOE presents awards for outstanding contributions, technical accomplishments and innovative research and development.

Dr. Zidan was honored for his contributions in developing electrochemical methods for alane regeneration. He was lead researcher on an SRNL project team that developed a novel closed cycle for producing the high capacity hydrogen storage material.

For years, one of the major obstacles to widespread commercialization of hydrogen and fuel cell technologies has been hydrogen storage. Solid-state storage, using solid materials such as metals that absorb hydrogen and release it as needed, has many advantages over storing hydrogen as a liquid or gas, and many storage materials have been examined trying to meet DOE’s technical targets. A combination of aluminum and hydrogen called aluminum hydride, also known as alane, possesses desired qualities as a storage material, but has been considered impractical because of the high pressures required to combine hydrogen and aluminum to re-form the hydride material after the hydrogen has been released. Alternate methods of production using chemical synthesis have typically produced stable metal chloride byproducts that make it practically impossible to regenerate the alane. The electrochemical cycle demonstrated by Dr. Zidan and the SRNL team for production of alane avoids both of these issues and provides an innovative promising option for further research and development.

Dr. Zidan came to SRNL in 2000 from the University of Hawaii. Since that time, he has led both basic science and applied research projects to advance the practicality of hydrogen as an energy alternative.

SRNL is DOE’s applied research and development national laboratory at SRS. SRNL puts science to work to support DOE and the nation in the areas of environmental management, national and homeland security, and energy security. The management and operating contractor for SRS and SRNL is Savannah River Nuclear Solutions, LLC.

July 8, 2010 - 6:40 AM No Comments