Japan's
Hitachi Maxell Ltd. (TSE:6810) has developed a proprietary cathode material
that helps significantly prolong the service life of solid-polymer fuel
cells by helping prevent the deterioration of the electrolyte material.
Thanks to this action, even small
fuel cells can provide more than 4,000 hours of service life, opening the
door to their practical application as small, portable power sources.
Using the new cathode material, Hitachi
Maxell plans to develop a portable power source that can be used in outdoor
settings and in emergencies.
It hopes to have ready by 2010 commercial
versions that use hydrogen derived from aluminum and water as the fuel
and can provide 10-100 watts of power.
In a solid-polymer fuel cell, hydrogen
ions generated at the cathode migrate through the electrolyte to the anode,
where they react with oxygen ions to form water. Platinum is attached to
the carbon electrode to catalyze the generation of oxygen ions. Because
the fuel cell is constantly being started and stopped, the bonds between
the carbon and platinum break over time and the platinum becomes free to
dissolve and move into the electrolyte, where it accumulates as an impurity,
hampering hydrogen ion migration and reducing the power output.
For the large fuel cells designed
for cars and homes, a special device can be attached to the fuel cell to
separate and remove the dissolved platinum. But this is not an option for
small, portable fuel cells.
Hitachi Maxell solved the problem
by developing a cathode material that uses an organic compound as an additive.
The oxygen from this organic compound interacts with the dissolved platinum
and keeps it inside the electrode, preventing the migration to the electrolyte
that degrades fuel cell performance.
In tests, fuel cells with the new
cathode retained 90 per cent of their original power output after 5,000
on-off cycles, whereas the performance of conventional fuel cells fell
more than 50 per cent.
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