Researchers
in Colorado are reporting the first successful “wiring up” of hydrogenase
enzymes. Those much-heralded proteins are envisioned as stars in a future
hydrogen economy where they may serve as catalysts for hydrogen production
and oxidation in fuel cells. Their report, describing a successful electrical
connection between a carbon nanotube and hydrogenase, is scheduled for
the Nov. issue of Nano Letters.
In the new study, Michael J. Heben,
Paul W. King, and colleagues explain that bacterial enzymes called hydrogenases
show promise as powerful catalysts for using hydrogen in fuel cells, which
can produce electricity with virtually no pollution for motor vehicles,
portable electronics, and other devices.
However, scientists report difficulty
incorporating these enzymes into electrical devices because the enzymes
do not form good electrical connections with fuel cell components. Currently,
precious metals, such as platinum, are typically needed to perform this
catalysis.
The researchers combined hydrogenase
enzymes with carbon nanotubes, submicroscopic strands of pure carbon that
are excellent electrical conductors. In laboratory studies, the researchers
demonstrated that a good electrical connection was established using photoluminescence
spectroscopy measurements.
These new “biohybrid” conjugates
could reduce the cost of fuel cells by reducing or eliminating the need
for platinum and other costly metal components, they say.
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