| TOTO Ltd.
has announced the development of home-use solid oxide fuel cell (SOFC)
with rated power generation of 700 W (photo). The field test of the fuel
cell is scheduled to start in 2008.
This SOFC mounts the cell featuring
the operating temperature of 500°C, which the company announced in
October 2005. The operating temperature of the product is at least 300°C
lower than that of the existing SOFC.
The lower operating temperature results
in thinner heat insulating material, hence smaller size. Further, because
the cell diameter is as small as 5 mm, it is less likely to be affected
by thermal strain due to temperature variation.
Thus, the new SOFC also supports
partial-load operation in which the output is lowered when less electricity
is required, such as at night. TOTO explains that partial-load operation
with the output reduced to 300 W has nearly the same efficiency as 700
W.
TOTO aims to achieve power generation
efficiency of more than 46% (AC transmission end efficiency; lower calorific
value standard) and heat recovery efficiency of 35% or higher for the power
generation system to be used in the field test.
The target volume of the system,
including the auxiliaries, is 130 L, equivalent to that of an outdoor type
air conditioning unit, and the target weight is 50 kg. The size of the
power generation module itself is 280 (H) x 480 (W) x 390 (D) mm (approx.
52 L).
In order for the cell to operate
at a temperature around 500°C, cerium oxide and lanthanum gallium oxide
are used for the electrolyte. This electrolyte has a problem; it reacts
with the nickel (Ni) in the fuel electrode during the firing process and
increases internal resistance, thus failing to achieve a sufficient electromotive
force.
TOTO reportedly succeeded in preventing
the reaction with Ni by forming a nickel cerium oxide as an intermediate
layer provided between the electrolyte and fuel electrode.
SOFC is expected to be the next-generation
home-use fuel cell because it boasts the power generation efficiency of
more than 45%. That percentage is about 10 points higher than that of PEFC,
which is currently under the large-scale field test for use as the residential
fuel cell.
Although SOFC has disadvantages such
as a high operating temperature, the long time required for startup and
shutdown, and breakage due to thermal strain, technical improvements are
rapidly being introduced, as indicated by TOTO's latest development.
It seems that SOFC is beginning to
outperform the PEFC, which has troubles in reducing the cost and extending
the life.
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