NAGOYA--The
Japan Fine Ceramics Center (JFCC) has collaborated with Noritake Co. (TSE:5331)
and others to develop a high-performance hydrogen separation membrane made
from ceramic materials.
The group has also developed a prototype
device based on this membrane that can attach directly to a gas pipeline
to supply hydrogen for fuel cells using city gas as the source.
The cylindrical membrane is roughly
3mm in diameter and is composed of three layers of ceramic materials with
progressively smaller pores. The inner layer is made from multiporous alumina
with pore sizes of roughly 150 nanometers. Surrounding this is a layer
made from a finer-grained ceramic with 4-8nm pores. The outer layer is
made from amorphous silica with pore sizes of around 0.3nm. Attached to
this layer are catalysts such as nickel and palladium.
When methane gas and steam are flowed
down the outside of the membrane, the catalysts drive a reaction that decomposes
the methane to yield hydrogen and carbon monoxide. The pores of the amorphous
silica are only large enough to allow the passage of hydrogen molecules,
which can be recovered from inside the cylinder.
The catalysts are so tightly attached
to the membrane that the reaction to generate hydrogen can be carried out
at a temperature of around 500 C, which is 300 degrees lower than normal.
The JFCC will continue its research
with the goal of having practical systems ready in fiscal 2020 that can
be used to supply hydrogen from city gas to fuel cells in homes and businesses,
as well as fuel cell cars at hydrogen filling stations.
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