University
of Delaware scientists are part of a team headed by Nuvera Fuel Cells Inc.
of Cambridge, Mass., that has won a $5 million U.S. Department of Energy
grant for research and development of fuel cells.
Michael H. Santare, professor of
mechanical engineering, and Anette M. Karlsson, assistant professor of
mechanical engineering, are leading efforts at the University.
The funding will support UD research
on polymer electrolyte membrane fuel cells (PEMFCs), which Santare said
have many potential benefits for transportation applications. Among those
benefits are increased fuel efficiency, lowered harmful emissions and a
reduction of the world's dependence on petroleum, he said.
However, Santare said there are still
a number of technical barriers that must be overcome before PEMFCs can
be commercially successful on a large scale. One of the most challenging
issues for PEMFC-powered vehicles is start-up and shut down in cold temperatures.
Because water transport through the
membrane is an essential part of the operation of the fuel cell, sub-freezing
temperatures can impose large stresses on the system as the water freezes,
Santare said. These stresses in turn can cause premature mechanical failure
of the fuel cell.
Furthermore, if water remains in
the system after shut down, it could freeze and further stress the system.
“The need for improved lifetime of
PEMFC necessitates that the freeze-thaw behavior be understood clearly
and that mechanical models be developed so that new materials and system
designs can be introduced to improve the cold temperature performance,”
Santare said.
“In automobile applications, the
requirement on durability is very high,” Karlsson said. “We don't expect
to have to take the car in for service once a month. In fact, we don't
expect to have to do anything to maintain the car. To ensure a reliable
design of a fuel cell, we must therefore understand how it behaves over
a long time, for all possible conditions. The fuel cell gets frozen several
times during the winter and might run very hot during operation in the
summer. Each extreme event accumulates a small damage and we must interpret
this damage into our models to predict how the material degrades with time.”
She said the grant “is an important
addition to the ongoing and growing effort in the mechanical engineering
department on clean energy, where more than half a dozen faculty members
are actively conducting research.“
In addition to Nuvera and UD, other
partners in the project are W.L. Gore & Associates and SGL Carbon Inc.
Santare has research interests in
applied mechanics and composite materials. He received a bachelor's degree
from Rensselaer Polytechnic Institute and a master's and doctorate from
Northwestern University. He joined the UD faculty in 1986 and was a Fulbright
Distinguished Visiting Professor at the Universidade do Porto in Portugal
in 2001.
Karlsson has interests in the thermo-mechanical
properties and response of advanced and traditional materials. She received
a doctorate in mechanical and aerospace engineering from Rutgers University
and conducted postdoctoral research at Princeton University before joining
the UD faculty in 2002. She is the recipient of the 2004 Office of Naval
Research Young Investigator Award and the 2005 Francis Alison Young Scholars
Award.
Another UD team, which is led by
Jingguang Chen, professor of chemical engineering and director of UD's
Center for Catalytic Science and Technology, and Brian Willis, assistant
professor of chemical engineering, are part of a team that received a $4.6
million Department of Energy grant to work on a different aspect of fuel
cell technology.
That team, which includes Pacific
Northwest National Laboratory, Oak Ridge National Laboratory and fuel cell
manufacturer Ballard Power Systems, is working to find ways in which hydrogen
fuel cells can be made less costly and more stable by using materials such
as tungsten carbide modified with low concentrations of platinum instead
of pure platinum.
Both grants were awarded through
the same Department of Energy program.
“The Department of Energy is committed
to breaking our addiction to oil by creating a diverse portfolio of clean,
affordable and domestically produced energy choices,” U.S. Energy Secretary
Samuel W. Bodman said in announcing the award, part of $100 million in
grants announced by the agency. “We expect hydrogen to play an integral
role in our energy portfolio, and we are eager to see hydrogen fuel cell
vehicles on the road in the near future.”
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