| TOKYO--A group
at the Tokyo University of Science has developed a more efficient means
of generating hydrogen from water via photocatalysts and visible light.
By using a special pair of photocatalysts
and adding a small amount of iron, the water can be completely dissociated,
and hydrogen can be generated in quantities up to 10 times greater than
current processes.
The innovation represents a step
forward in the quest to make hydrogen for fuel cells using only water and
sunlight, without any need for fossil fuels.
The two photocatalysts are bismuth
vanadate and strontium titanate with added rhodium. The strontium titanate
is also surface-coated with ruthenium.
When combined, the two photocatalysts
can absorb light in wavelengths as great as 520 nanometers. Harnessing
more of the light spectrum for the dissociation of water yields more hydrogen.
The iron assists in the exchange of electrons, helping to completely dissociate
the water molecules.
In one experiment, 50mg of each photocatalyst
and around 0.3mg of iron were added to 120ml of water. The water was then
exposed to a light source simulating sunlight. The yield was equivalent
to 180ml of hydrogen per hour per square meter of area exposed to the light
source.

|