University
of Hawai'i researcher Michael Antal has developed a working fuel cell that
uses charcoal as its fuel and operates at bread-baking temperatures.
The Antal system, which he calls
an aqueous alkali biocarbon fuel cell, is unlike other fuel cell technology
both in that it uses a renewable fuel and that it does not require particularly
high temperatures.
Renewable energy is the watchword
in the modern energy debate, an effort pushed in large part by high global
oil prices and the perception that global political instability threatens
the availability of fuel.
Gov. Linda Lingle is backing a package
of bills in the Legislature that includes strong support for renewables,
and President Bush has been on the stump in recent weeks on behalf of energy
initiatives that include hydrogen fuel cell cars, solar power, wind research,
and more.
Most research today focuses on cells
fueled with hydrogen, which must be manufactured— in many cases from fossil
fuels.
But "this is effectively a battery
that uses charcoal to make electricity," Antal said.
The technology has attracted interest
from around the world, said Dick Cox, director of the university's Office
of Technology Transfer and Economic Development.
"I think it's a tremendous innovation,"
Cox said. His office will license the technology to independent companies,
which would pay Antal and the university for the use of the system.
Antal's cell operates at about 400
degrees Fahrenheit. By contrast, a carbon cell developed by the Lawrence
Livermore National Laboratory operates at 1,500 degrees.
"People have been building hydrogen
fuel cells for over a century. Our purpose is to awaken people to the fact
that there are new things out there. We need to think outside the box,"
Antal said.
The key to his cell's operation is
the very chemically reactive property of charcoal, which has a large surface
area and burns at relatively low temperatures, he said.
Antal
said he imagines industrial applications would be most appropriate for
the fuel cell, but figures it might be capable of running an automobile.
Antal's former associate, University of Tokyo researcher Kazuhiro Mochidzuki,
said the system appears most appropriate for mid-sized power generation
stations.
"Power generation by carbon fuel
cell should not be in so big scale. The dispersed power system that does
not require big generators is suitable for the carbon fuel cell," Mochidzuki
said via e-mail.
Right now, his lab at the University
of Hawai'i is fine-tuning the design, and looking for companies that would
finance the development of a commercial charcoal fuel cell. Mochidzuki
said there are still technical issues to be resolved.
"Carbon fuel cell is one of the promising
technologies to obtain power from charcoal at a high efficiency. It can
be said that the carbon fuel cell is an important technology to promote
the sustainable biomass energy system," he said. However, "there are a
number of problems to be solved against its practical use of carbon fuel
cell, even if it theoretically has a good potential."
The carbon cell functions something
like a car battery. It has an anode and cathode positive- and negative-charged
terminals in a liquid solution, and if you put an electrical load — like
a light bulb — between them, electrical current flows from one to the other.
But that's where the similarity ends.
In Antal's cell, the electrolyte
is alkaline potassium hydroxide, not sulphuric acid. It is kept under pressure
to prevent it from boiling away at 400 degrees. The negative terminal,
or cathode, which acts as a catalyst, is made of nickel and silver or platinum.
The positive terminal, or anode,
is a porous ceramic column filled with charcoal powder. A piston keeps
it pressurized, and serves at the attachment point for the electrical connection.
In operation, hydroxide ions in the
electrolyte attack the carbon, creating carbon dioxide and water. The process
releases energy.
The cell is fed air to provide the
process with new oxygen, and it vents carbon dioxide.
The charcoal does not burn in the
sense of a campfire burning. The reaction occurs entirely within the liquid
of the fuel cell.
While fossil-fuel cells also produce
carbon dioxide, a greenhouse gas, charcoal represents a sustainable source
of fuel, since the living plants that produce the charcoal get their carbon
by removing carbon dioxide from the atmosphere.
Antal said that water-based or aqueous
fuel cells have a considerable history. A hydrogen-based aqueous fuel cell
was used in the first Apollo space mission.
While his charcoal fuel cell works
as it is, Antal said it needs to be more efficient, and his team is now
fine tuning it — working with different catalysts, different electrolyte
strengths and other changes. They also need to figure out how to continuously
feed charcoal fuel to the system.
"Handling of solid fuel, such as
charcoal, is not easy. If we want to feed charcoal into the cell continuously,
we have to solve the problem how it can be fed. This is one of the biggest
problems of solid fuel," Mochidzuki said.
Antal, who holds the University of
Hawai'i's Coral Industries Chair of Renewable Energy Resources, is a longtime
advocate of charcoal. Another of his projects is a flash carbonization
reactor, which converts biomass like macadamia nut shells, wood and grass
into charcoal. That charcoal can be used to cook food, as a filter or,
in tandem with the new fuel cell, as a source of electricity.

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